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Numbering is based on the a-terpinyl cation shown in Scheme 3 Product limonene terpinolene a-terpineol 1,8-cineole bornyl diphosphate camphene a-pinene b-pinene endo-fenchol b-phellandrene a-terpinene g-terpinene a-thujene sabinene sabinene hydrate 3-carene Mechanism deprotonation deprotonation capture of C8 cation by water capture of C8 cation by water, C8-C1 ether linkage C1-C8 ring closure, C2 cation capture by diphosphate C1-C8 ring closure, WM rearrangement, deprotonation C2-C8 germinal closure, deprotonation C2-C8 ring closure, deprotonation C2-C8 termminal closure, WM rearrangement, C2 cation nse now trading terminal by water 1,3 hydride shift, deprotonation 1,2 hydride shift, deprotonation 1,2 hydride shift, deprotonation 1,2 hydride shift, C2-C4 nse now trading terminal closure, deprotonation 1,2 hydride shift, C2-C4 ring closure, deprotonation 1,2 hydride shift, C2-C4 ring closure, C1 capture by water deprotonation-mediated C5-C8 ring closure Reference 25 32 15 41, 42 43 32, 44 31 31 29 32, 45 45 45 46 47 30 48 The liver (see Fig.

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